Chlorido(2-methyl-4-oxo-4H-pyran-3-olato-κ 2 O 3,O 4)(1,10-phenanthroline-κ 2 N,N′)copper(II)
نویسندگان
چکیده
The copper(II) atoms in the two independent mol-ecules of the title compound, [Cu(C(6)H(5)O(3))Cl(C(12)H(8)N(2))], both adopt square-pyramidal geometries. The two coordinating atoms of the two heterocyclic ligands comprise the square plane, and the chlorine atom occupies the apical position of the coordination environment.
منابع مشابه
(2-Methyl-4-oxo-4H-pyran-3-olato-κ2 O 3,O 4)bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1)
In the title compound, [Cu(C(6)H(5)O(3))(C(18)H(15)P)(2)]·C(18)H(15)P·CH(3)OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138 Å), with the Cu(I) atom 0.451 (5) Å out of the plane. The Cu(I) atom has a distorted tetra-hedral coordination. The O-Cu-O angle is 80.07 (8)° and the P-Cu-P angle is 123.49 (3)°. The crystal packing is stablized by intra-molecular C-H⋯O inter-act...
متن کاملDiethyl(μ3-2-methyl-4-oxo-4H-pyran-3-olato-κ4 O 3,O 4:O 3:O 3)tris(μ2-2-methyl-4-oxo-4H-pyran-3-olato-κ3 O 3,O 4:O 3)trizinc toluene disolvate
The title compound, [Zn3(C2H5)2(C6H5O3)4]·2C7H8, crystallizes with one complex mol-ecule solvated by two mol-ecules of toluene in the asymmetric unit. The Zn(II) ions are coordinated by two terminal ethyl (Et) groups and four maltolate ligands, which act as μ3- and μ2-bridges. The metal atoms are arranged in an incomplete cubane Zn3O4 core structure, derived from one EtZnO3 tetra-hedron, one Et...
متن کاملChlorido(1,10-phenanthroline)[1,1,1-trifluoro-3-(2-thenoyl)acetonato]copper(II)
In the title compound, [Cu(C(8)H(4)F(3)O(2)S)Cl(C(12)H(8)N(2))], the Cu(II) ion exhibits a distorted square-pyramidal geometry. The coordination environment of the cation comprises two N atoms from 1,10-phenanthroline and two O atoms from thenoyltrifluoro-acetone in the basal plane and one Cl(-) anion at the apical site. There are weak inter-molecular C-H⋯Cl bonds.
متن کاملThe chain structure of [Ni(C4H2O4)(C12H8N2)(H2O)]n with different types of fumarate bridging
Using modified solvothermal conditions (longer cooling time), beside previously characterized dark-green crystals of [Ni(C(4)H(2)O(4))(C(12)H(8)N(2))] (main product), a few light-green crystals of the polymeric title compound, catena-poly[[aqua-(1,10-phenanthroline-κ(2)N,N')nickel(II)]-μ-fumarato-κ(2)O:O'-[aqua-(1,10-phenanthroline-κ(2)N,N')nickel(II)]-μ-fumarato-κ(4)O,O':O'',O'''], [Ni(C(4)H(2...
متن کاملBis[μ-3-(2-hydroxyethyl)-2-methyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato-κ3 N,O:O]bis[aquachloridocopper(II)]
In the dinuclear centrosymmetric copper(II) title compound, [Cu(2)(C(11)H(11)N(2)O(2))(2)Cl(2)(H(2)O)(2)], each Cu(II) ion has a slightly distorted trigonal-bipyramidal geometry and is coordinated by one N and one O atom from one 3-(2-hydroxy-ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olate ligand, another O atom from the second ligand, one water mol-ecule and one Cl atom. The crystal struct...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008